UKHUSELEKO I-DATHA ISHEETHI

Ngokohlaziyo lwesi-8 lwe-UN GHS

Inguqulelo: 1.0

Umhla wokudalwa: Julayi 15, 2019

Umhla wohlaziyo: Julayi 15, 2019

ICANDELO 1: Ukuchongwa

1.1GHS Isazisi seMveliso

1.2Ezinye iindlela zokuchonga

1.3Usetyenziso olucetyiswayo lwekhemikhali kunye nezithintelo ekusebenziseni

1.4Iinkcukacha zomthengisi

1.5Inombolo yefowuni yexesha likaxakeka

ICANDELO 2: Ukuchongwa kwengozi

2.1 Ukuhlelwa kwezinto okanye umxube

Ulwelo olunokutsha, Udidi loku-1

Ubuthi obubukhali - udidi 3, ngomlomo

Ubuthi obubukhali - udidi 3, iDermal

Ukucaphuka kolusu, iCandelo 2

Ukucaphuka kwamehlo, iCandelo 2

Ubuthi obubukhali - Udidi 2, Ukuphefumla

Ityhefu ethile yelungu ekujoliswe kuyo - ukuba sesichengeni okukodwa, uDidi 3

Inobungozi kwindalo yasemanzini, ixesha elifutshane (Acute) – Udidi lweAcute 1

Inobungozi kwindalo yasemanzini, ixesha elide (Ezingapheliyo) – Udidi lwezigulo 1

I-2.2GHS iileyibhile zeeleyibhile, kubandakanywa neengxelo zokhuseleko

2.3Ezinye iingozi ezingaphumeleliyo kuhlelo

akukho datha ekhoyo

ICANDELO 3: Ukwakhiwa/ulwazi ngezithako

3.1 Izinto

ICANDELO 4: Amanyathelo oncedo lokuqala

4.1 Inkcazo yamanyathelo oncedo lokuqala ayimfuneko

Ukuba uphefumlelwe

Umoya omtsha, phumla. Isiqingatha-emi nkqo. Bhekisela kunyango.

Ukulandela uqhagamshelwano lwesikhumba

Susa iimpahla ezingcolisekileyo. Hlanza ulusu ngamanzi amaninzi okanye ishawa. Bhekisela kunyango .

Ukulandela ukudibana kwamehlo

Pula ngamanzi amaninzi kangangemizuzu emininzi (susa iilensi zoqhagamshelwano ukuba kunokwenzeka ngokulula). Yiya kunyango ngoko nangoko.

Ukulandela ukungeniswa

Hlamba umlomo. MUSA ukugabha. Nika iglasi enye okanye ezimbini zamanzi zokusela. Bhekisela kunyango .

4.2Ezona mpawu zibalulekileyo/iziphumo, ezibukhali kwaye zilibazisekile

Isicatshulwa kwiSikhokelo se-ERG 131 [Ulwelo olunokutsha - olunetyhefu]: I-TOXIC; Isenokubulala xa irholiwe, ityiwe okanye ifunxwe ngolusu. Ukuphefumla okanye ukudibana nezinye zezi zinto kuya kucaphukisa okanye kutshise ulusu namehlo. Umlilo uya kuvelisa iigesi ezicaphukisayo, ezonakalisayo kunye/okanye ezinetyhefu. Umphunga unokubangela isiyezi okanye ukufuthaniselwa. Amanzi aphuma kulawulo lomlilo okanye amanzi adilulisiweyo anokubangela ungcoliseko. (ERG, 2016)

4.3 Inkcazo yonyango olukhawulezileyo kunye nonyango olulodwa olufunekayo, ukuba kuyimfuneko

Uncedo lokuqala olukhawulezileyo: Qinisekisa ukuba ukukhutshwa kwentsholongwane okwaneleyo kuye kwenziwa. Ukuba isigulana asiphefumli, qalisa ukuphefumla okwenziwayo, ngokukhethekayo nge-resuscitator yevalvu efunwayo, isixhobo semaski yengxowa-valve, okanye isigqubuthelo sepokotho, njengoko uqeqeshiwe. Yenza i-CPR njengoko kuyimfuneko. Ngoko nangoko gungxula amehlo angcolisekileyo ngamanzi ahamba kakuhle. Musa ukukugabha. Ukuba ukuhlanza kwenzeka, isigulane sincike phambili okanye sibeke kwicala lasekhohlo (indawo yentloko-ezantsi, ukuba kunokwenzeka) ukugcina umoya ovulekileyo kunye nokuthintela ukulangazelela. Gcina isigulane sithule kwaye ugcine ubushushu bomzimba obuqhelekileyo. Fumana unyango. Ketones kunye neekhompawundi ezinxulumene

ICANDELO 5: Amanyathelo okucima umlilo

5.1Izixhobo zokucima umlilo ezifanelekileyo

Ukuba izinto zisemlilweni okanye zibandakanyeka emlilweni: Musa ukuwucima umlilo ngaphandle kokuba amanzi anokupheliswa. Ukucima umlilo usebenzisa i-arhente elungele uhlobo lomlilo olujikelezileyo. (Impahla ngokwayo ayitshi okanye itshise ngobunzima.) Pholisa zonke izikhongozeli ezichaphazelekayo ngobuninzi bamanzi aphuphumayo. Galela amanzi ukusuka kude kangangoko. Sebenzisa ugwebu, imichiza eyomileyo, okanye ikharbon diokside. Gcina amanzi aphumayo kwimijelo ephantsi komhlaba ehambisa amanzi amdaka kunye nemithombo yamanzi. I-Chloroacetone, izinzile

5.2 Iingozi ezithile ezivela kwikhemikhali

Icatshulwe kwiSikhokelo se-ERG 131 [Ulwelo olunokutsha - olunetyhefu]: LUYA KUNOTSHEKA KAKHULU: Luya kutshiswa lula bubushushu, iintlantsi okanye amadangatye. Umphunga usenokwenza imixube eqhumayo ngomoya. Umphunga unokuhamba uye kwindawo yokulayita kunye nokubuyela umva. Imiphunga emininzi inzima kunomoya. Ziya kusasazeka emhlabeni kwaye ziqokelele kwiindawo eziphantsi okanye ezivaliweyo (i-sewers, i-basement, iitanki). Ukudubula komphunga kunye nobungozi betyhefu ngaphakathi, ngaphandle okanye kwimijelo ephantsi komhlaba ehambisa amanzi amdaka. Ezo zinto zenziwe nge-(P) zinokugqabhuka ziqhume xa zishushu okanye zibandakanyeka emlilweni. Ukuqengqeleka kumjelo ophantsi komhlaba ohambisa amanzi amdaka kungadala ingozi yomlilo okanye ugqabhuko-dubulo. Izikhongozeli zinokugqabhuka xa zishushu. Ulwelo oluninzi lukhaphukhaphu kunamanzi. (ERG, 2016)

5.3Izenzo ezikhethekileyo zokukhusela kubacimi bomlilo

Sebenzisa isitshizi samanzi, umgubo, ugwebu olumelana notywala, ikharbon diokside. Xa kutsha: gcina amagubu, njl., pholisa ngokutshiza ngamanzi.

ICANDELO 6: Amanyathelo okukhululwa ngengozi

6.1 Izilumkiso zomntu, izixhobo zokukhusela kunye neenkqubo zongxamiseko

Susa yonke imithombo yokutshisa. Phuma kwindawo enobungozi! Qhagamshelana nengcali! Ukhuseleko lomntu: isihluzi sokuphefumla serhasi eziphilayo kunye nomphunga olungelelaniswe kugxininiso lomoya wento. Ukungenisa umoya. Qokelela ulwelo oluvuzayo kwizikhongozeli ezigqunyiweyo. Funxa ulwelo olushiyekileyo esantini okanye kwisifunxa esingangeni. Emva koko gcina kwaye ulahle ngokwemigaqo yendawo.

6.2 Izilumkiso zokusingqongileyo

Susa yonke imithombo yokutshisa. Phuma kwindawo enobungozi! Qhagamshelana nengcali! Ukhuseleko lomntu: isihluzi sokuphefumla serhasi eziphilayo kunye nomphunga olungelelaniswe kugxininiso lomoya wento. Ukungenisa umoya. Qokelela ulwelo oluvuzayo kwizikhongozeli ezigqunyiweyo. Funxa ulwelo olushiyekileyo esantini okanye kwisifunxa esingangeni. Emva koko gcina kwaye ulahle ngokwemigaqo yendawo.

6.3 Iindlela kunye nezixhobo zokuthintela kunye nokucoca

Iingqwalasela zokusingqongileyo - ukuchitheka komhlaba: Yomba umngxuma, ichibi, ichweba, indawo yokugcina izinto ezingamanzi okanye eziqinileyo. /SRP: Ukuba ixesha liyavuma, imingxuma, amachibi, amachibi, imingxuma emanzi, okanye iindawo zokubamba kufuneka zitywinwe nge-membrane ethambileyo liner ethambileyo. Funxa ulwelo oluninzi ngothuthu lwempukane, umgubo wesamente, okanye izinto zokurhweba. I-Chloroacetone, izinzile

ICANDELO 7: Ukuphatha nokugcina

7.1Amanyathelo okuthintela ukuphathwa ngokukhuselekileyo

AKUKHO amadangatye avulekileyo, AKUKHO iintlantsi kwaye AKUKHO msi. Ngaphezulu kwe-35°C kusetyenziswa isixokelelwano esivaliweyo, umoya kunye nezixhobo zombane ezingaqhushumba. Ukuphatha kwindawo engena umoya. Nxiba iimpahla ezifanelekileyo zokuzikhusela. Kuphephe ukudibana nolusu namehlo. Kuphephe ukubunjwa kothuli kunye ne-aerosols. Sebenzisa izixhobo ezingatshisiyo. Thintela umlilo obangelwa ngumphunga wokukhupha i-electrostatic.

7.2Imiqathango yogcino olukhuselekileyo, kuquka nakuphi na ukungahambelani

Gcina kuphela xa uzinzile. Ukuthintela umlilo. Yahlulwe kwii-oxidants ezinamandla kunye nokutya kunye nesondlo. Gcina ebumnyameni.Gcina kuphela xa uzinzisiwe. Ukuthintela umlilo. Yahlulwe kwii-oxidants ezinamandla, ukutya kunye nesondlo. Gcina ebumnyameni … Ngaphezulu kwe-35 deg C sebenzisa isixokelelwano esivaliweyo, umoya ongenisa umoya, kunye nezixhobo zombane ezingagqabhuki.

ICANDELO 8: Ulawulo lokuvezwa/ukhuseleko lomntu

8.1Iiparamitha zokulawula

Amaxabiso omda wokuBoniso eMsebenzini

TLV: 1 ppm njenge STEL; (ulusu)

Amaxabiso amiselweyo ebhayoloji

akukho datha ekhoyo

8.2Ulawulo lobunjineli olufanelekileyo

Qinisekisa ukungena komoya okwaneleyo. Bamba ngokuhambelana nococeko olululo lwamashishini kunye nokuziqhelanisa nokhuseleko. Misela iindawo zokuphuma ezingxamisekileyo kunye nommandla wokuphelisa umngcipheko.

8.3 Amanyathelo okhuseleko lomntu ngamnye, njengesixhobo sokukhusela umntu (PPE)

Ukhuseleko lwamehlo / ubuso

Nxiba isikhuselo sobuso okanye isikhuselo samehlo ngokudityaniswa nokhuseleko lokuphefumla.

Ukukhuselwa kwesikhumba

Iiglavu ezikhuselayo. Impahla ekhuselayo.

Ukhuseleko lokuphefumla

Sebenzisa umoya, umbhobho wasekuhlaleni okanye ukhuseleko lokuphefumla.

Iingozi zobushushu

akukho datha ekhoyo

ICANDELO 9: Iimpawu zomzimba kunye neekhemikhali kunye neempawu zokhuseleko

ICANDELO LE-10: Uzinzo kunye nokusebenza kwakhona

10.1Ukwenzeka kwakhona

Umxube kancinane upholima phantsi kweempembelelo zokukhanya. Oku kudala ingozi yomlilo okanye ugqabhuko-dubulo. Ibola xa ifudunyezwa naxa itshiswa.

10.2Uzinzo kwiChemical

Ijike ibe mnyama kwaye ihlaziyeke xa kuvele ukukhanya ixesha elide, kunokuzinziswa nge-0.1% yamanzi okanye i-1.0% ye-calcium carbonate.

10.3Ukwenzeka kweentshukumo ezinobungozi

Inokutsha xa ibekwe kubushushu okanye kwidangatye, okanye i-oxidizers.CHLOROACETONE iba mnyama kwaye iphinde ikhanye xa kuvele ukukhanya ixesha elide [Merck]. Oku kwenzeka kwibhotile ngexesha lokugcinwa iminyaka emibini kwi-shelf ekukhanyeni okusasazekayo. Kwiintsuku ezimbalwa emva kokuba ibhotile isusiwe, yaqhuma [Ind. Eng. Iindaba 9: 184(1931)]. Izinziswa ngokongezwa kwe-0.1% yamanzi okanye i-0.1% yeCaCO3.

10.4Iimeko ekufuneka uzithintele

akukho datha ekhoyo

10.5Izinto ezingahambelaniyo

INGXELO YOBOMI YEKHEMIKALI: Ukukwazi ukuzibamba. I-Chloroacetone iye yajika yaba mnyama ngexesha lokugcinwa iminyaka emibini kwi-self in diffused light. Kwiintsuku ezimbalwa emva kokuba ibhotile ye-chloroacetone isusiwe, yaqhuma. I-chloroacetone yayipholymerized ibe yinto emnyama efana ne-Ind. Eng. Iindaba 9: 184(1931). (REACTIVITY, 1999)

10.6Imveliso eyingozi yokubola

Xa ishushu ukuze ibole ikhupha umsi onetyhefu kakhulu.

ICANDELO LE-11: Ulwazi lwe-Toxicological

Ityhefu ebukhali

• Umlomo: LD50 Rat ngomlomo 100 mg / kg
• Ukuphefumla: LC50 Impuku yokuphefumla 262 ppm/1 hr
• Dermal: akukho data ekhoyo

Ukonakala kolusu/ukucaphuka

akukho datha ekhoyo

Umonakalo omkhulu wamehlo / ukucaphuka

akukho datha ekhoyo

Ukuphefumla okanye ukuvuselela ulusu

akukho datha ekhoyo

I-germ cell mutagenicity

akukho datha ekhoyo

I-Carcinogenicity

akukho datha ekhoyo

Ubuthi bokuzala

akukho datha ekhoyo

STOT-enye yokuvezwa

Lachrymation. Lo mxube ucaphukisa kakhulu amehlo, ulusu kunye nomjelo wokuphefumla.

STOT-utyhileko oluphindaphindiweyo

akukho datha ekhoyo

Umngcipheko wokufuna

Ungcoliseko oluyingozi lomoya lunokufikelelwa ngokukhawuleza ekuphuhliseni le nto kuma-20°C.

ICANDELO LE-12: Ulwazi ngendalo

12.1Ityhefu

• Ubuthi kwintlanzi: akukho datha ekhoyo
• Ubuthi kwi-daphnia kunye nezinye izilwanyana ezingenamqolo zasemanzini: akukho datha ekhoyo
• Ubutyhefu kwi-algae: akukho datha ekhoyo
• Ubuthi kwi-microorganisms: akukho datha ekhoyo

12.2 Ukuzingisa kunye nokuthotywa

akukho datha ekhoyo

12.3Isakhono seBioaccumulative

I-BCF eqikelelwayo ye-3 ibalwe kwintlanzi ye-1-chloro-2-propanone (SRC), isebenzisa i-log eqikelelwayo ye-Kow ye-0.02 (1) kunye ne-equation-derived equation (2). Ngokweskimu sohlelo(3), le BCF icebisa ukuba amandla e-bioconcentration kwizinto eziphilayo zasemanzini asezantsi(SRC).

12.4Ukushukuma emhlabeni

Ukusebenzisa indlela yoqikelelo lwesakhiwo esekelwe kwizalathisi zokuxhulumana kweemolekyuli (1), i-Koc ye-1-chloro-2-propanone inokuqikelelwa ukuba yi-5 (SRC). Ngokwenkqubo yokuhlelwa (2), eli xabiso eliqikelelweyo le-Koc libonisa ukuba i-1-chloro-2-propanone kulindeleke ukuba ibe nokuhamba okuphezulu kakhulu emhlabeni.

12.5Ezinye iziphumo ezibi

akukho datha ekhoyo

ICANDELO LE-13: Iingqwalasela zokulahla

13.1Iindlela zokulahla

Imveliso

Izinto eziphathekayo zinokulahlwa ngokususwa kwiplanti yokutshatyalaliswa kweekhemikhali ezinelayisensi okanye ngokutshiswa ngokulawulwa ngokukhuhla kwegesi yombane. Musa ukungcolisa amanzi, ukutya, ukutya okanye imbewu ngokugcina okanye ukulahla. Musa ukukhupha kwiinkqubo zogutyulo.

Ukupakishwa okungcolisekileyo

Izikhongozeli zingahlanjululwa kathathu (okanye zilingane) kwaye zinikezelwe ukuze zihlaziywe okanye zilungiswe kwakhona. Kungenjalo, isingxobo sinokugqobhozwa ukuze singasetyenziselwa ezinye iinjongo kwaye emva koko ilahlwe kwindawo yokulahla inkunkuma ecocekileyo. Ukutshiswa okulawulwayo ngokukhuhla kwerhasi ye-flue kunokwenzeka kwizinto zokupakisha ezinokutsha.

ICANDELO LE-14: Ulwazi lwezothutho

14.1Inombolo yeUN

14.2Igama le-UN elichanekileyo lokuThumela

14.3I(ii)klasi zengozi yezothutho

14.4Iqela lokupakisha, ukuba likhona

14.5Iingozi zendalo esingqongileyo

14.6Amanyathelo okhuseleko akhethekileyo kumsebenzisi

akukho datha ekhoyo

14.7Ukuthuthwa ngobuninzi ngokwezixhobo ze-IMO

akukho datha ekhoyo

ICANDELO LE-15: Ulwazi lolawulo

15.1 Ukhuseleko, impilo kunye nemithetho yokusingqongileyo ejolise ngqo kwimveliso ekuthethwa ngayo

ICANDELO LE-16: Olunye ulwazi

Ulwazi ngohlaziyo

Izifinyezo kunye nezifinyezo

• I-CAS: Inkonzo yeeNgcaciso zeMichiza
• ADR: IsiVumelwano saseYurophu malunga nokuThuthwa kweMpahla eyiNgozi yaMazwe ngaMazwe ngeNdlela
• I-RID: Ummiselo ophathelele kwi-International Carriage ye-Dangerous Goods by Rail
• IMDG: IiMpahla ezinobungozi zaseLwandle zaMazwe ngaMazwe
• IATA: Umbutho woThutho loMoya wamazwe ngamazwe
• TWA: Ixesha elinobunzima obuphakathi
• I-STEL: Umda wokuvezwa kwexesha elifutshane
• I-LC50: Ukuxiliswa kweLethal 50%
• LD50: Idosi ebulalayo 50%
• EC50: Ugxininiso olusebenzayo 50%
• IPCS – Amakhadi oKhuseleko lweMichiza yaMazwe ngaMazwe (ICSC), iwebhusayithi: http://www.ilo.org/dyn/icsc/showcard.home
• I-HSDB-iBhanki yeDatha yeZinto eziBubungozi, iwebhusayithi: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
• IARC – I-Arhente yeHlabathi yoPhando ngoMhlaza, iwebhusayithi: http://www.iarc.fr/
• I-eChemPortal – iGlobal Portal to Information on Chemical Substances yi-OECD, iwebhusayithi: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
• I-CAMEO Chemicals, iwebhusayithi: http://cameochemicals.noaa.gov/search/simple
• I-ChemIDplus, iwebhusayithi: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
• I-ERG – Incwadi yesiKhokelo yokuPhendula kwiNgxamiseko yeSebe lezoThutho lase-US, iwebhusayithi: http://www.phmsa.dot.gov/hazmat/library/erg
• EJamani iGESTIS-database yezinto ezinobungozi, iwebhusayithi: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
• I-ECHA - i-Arhente yeMichiza yaseYurophu, iwebhusayithi: https://echa.europa.eu/

Iimbekiselo

Olunye Ulwazi

Emva kokudibana nolwelo lwamadyunguza kunokulibaziseka de kudlule iiyure ezininzi.Imida yokuqhushumba ayaziwa kuncwadi, nangona into enokutsha kwaye ine-flash point <61°C.Ixabiso lomda wokuvezwa emsebenzini akufanele ligqithwe nangayiphi na indawo utyhileko olusebenzayo.Isilumkiso sevumba xa kugqithwa ixabiso eliqingqiweyo lokuvezwa alanelanga.Isixhobo sokuzinzisa okanye isithinteli esongezelelweyo sinokuphembelela iimpawu ze-toxicological zale nto; dibana nengcali.

Nayiphi na imibuzo malunga nale SDS, Nceda uthumele umbuzo wakhoinfo@mit-ivy.com